Details
Fine Chemicals through Heterogeneous Catalysis
1. Aufl.
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CHF 215.00 |
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| Verlag: | Wiley-VCH (D) |
| Format: | |
| Veröffentl.: | 11.07.2008 |
| ISBN/EAN: | 9783527612970 |
| Sprache: | englisch |
| Anzahl Seiten: | 636 |
DRM-geschütztes eBook, Sie benötigen z.B. Adobe Digital Editions und eine Adobe ID zum Lesen.
Beschreibungen
Nowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production.<br> With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field.<br>
Introduction<br /> BASIC PRINCIPLES<br /> General considerations and types of catalysts<br /> Preparation of solid catalysts<br /> Characterization of solid catalysts<br /> SOLID ACID CATALYSTS: GENERAL<br /> Acidic clays<br /> Zeolithes<br /> Sulfonated polysiloxanes<br /> Silica-occluded heteropolyacids<br /> Hybrid sulfonated mesoporous systems<br /> The use of nafion and nafion/silica composites in solid acid catalysis<br /> SOLID ACID CATALYSTS: AROMATIC SUBSTITUTION<br /> Nitration of aromatics<br /> Halogenation over solid catalysts<br /> Friedel-Crafts alkylation<br /> Friedel-Crafts acylation<br /> Hydroxyalkylations<br /> Fischer indole synthesis<br /> SOLID ACID CATALYSTS: REARRANGEMENT & ISOMERIZATIONS<br /> Beckmann rearrangement<br /> Benzamine rearrangement<br /> Fries rearrangement<br /> Rearrangement of epoxides<br /> Pinacol rearrangement<br /> Terpene rearrangement/isomerization<br /> SOLID ACID CATALYSIS: MISCELLANEOUS<br /> Selective N-alkylation of amines with alcohols over gamma-alumina<br /> Alkylation of carbohydrates<br /> Heterocyclic synthesis<br /> Heterogeneous catalysis of Diels-Alder reactions<br /> Dehydration of alcohols<br /> SOLID BASE CATALYSIS<br /> Zeolithes and related materials in Knoevenagel condensations and Michael additions<br /> Hydrotalcite catalyzed aldol condensations<br /> Organic bases attached to mesoporous silicas as solid catalysts<br /> CATALYTIC HYDROGENATION AND DEHYDROGENATION<br /> Alkynes<br /> Aldehydes and ketones<br /> Carboxylic acids and derivatives<br /> Carbohydrates<br /> Aromatic nitro compounds<br /> Catalytic hydrogenation of aromatic rings<br /> Hydrogenolysis of C-O, C-N and C-X bonds<br /> Dehydrogenation<br /> Meerwein-Ponndorf-Verley reduction, Oppenauer Oxidation and related reactions<br /> Enantioselective hydrogenation with solid catalysts<br /> Metal-catalyzed amination of alcohols<br /> OXIDATION<br /> Epoxidation<br /> Oxidation of carbohydrates an metal catalysts<br /> Allylic and benzylic oxidation<br /> Ammoxidation of aromatic side-chains<br /> Aromatic ring hydroxylation<br /> C-C BOND FORMATION<br /> Carbon-carbon bond formation via surface organometallic chemistry (SOMC)<br /> Olefin metathesis<br /> Heck coupling<br /> Future Outlook
"Recommended reading for all industrial chemists!" Organic Process Research & Development
<p><b>Roger Arthur Sheldon</b> FRS FRSC is Emeritus Professor of Biocatalysis and Organic Chemistry at Delft University of Technology in the Netherlands.</p> <p><b>Herman van Bekkum</b> is the editor of <i>Fine Chemicals through Heterogeneous Catalysis</i>, published by Wiley.</p>
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